Apologies for the late reply, I posted yesterday but obviously it didn't work..

gzt:
Tried deleting all NIC adaptors and restart, they all appeared back by themselves, not sure if that was expected? In anycase no change.

shk292:
Tried both OpenDNS and Google for the IPV4 and 6 but no luck.

ckc:
Computer is an Emachine E640G, AMD Athlon II X2 P340 2.2GHz, ATI Mobility Radeon HD 5470, 4GB DDR3 Mem, Adaptors are: Atheros AR5B97 Wireless, Broadcom Netlink Gigabit Ethernet, Microsoft Virtual Wifi Miniport. Running Windows 7 64bit

From Task Manager:

Image Name PID Session Name Session# Mem Usage
========================= ======== ================ =========== ============
System Idle Process 0 Services 0 24 K
System 4 Services 0 2,964 K
smss.exe 272 Services 0 716 K
avgrsa.exe 388 Services 0 46,892 K
csrss.exe 724 Services 0 2,716 K
wininit.exe 776 Services 0 1,244 K
csrss.exe 800 Console 1 41,092 K
services.exe 844 Services 0 6,704 K
lsass.exe 860 Services 0 10,640 K
lsm.exe 872 Services 0 2,684 K
winlogon.exe 924 Console 1 3,616 K
svchost.exe 108 Services 0 5,928 K
svchost.exe 720 Services 0 7,440 K
atiesrxx.exe 364 Services 0 1,788 K
svchost.exe 1092 Services 0 19,428 K
svchost.exe 1128 Services 0 156,612 K
svchost.exe 1172 Services 0 15,888 K
svchost.exe 1204 Services 0 37,692 K
svchost.exe 1312 Services 0 2,464 K
svchost.exe 1452 Services 0 14,020 K
spoolsv.exe 1580 Services 0 6,760 K
svchost.exe 1620 Services 0 13,672 K
armsvc.exe 1704 Services 0 1,056 K
AppleMobileDeviceService. 1724 Services 0 4,252 K
avgidsagent.exe 1788 Services 0 19,284 K
avgwdsvc.exe 1808 Services 0 17,288 K
mDNSResponder.exe 1828 Services 0 3,576 K
SkypeC2CAutoUpdateSvc.exe 1848 Services 0 2,012 K
SkypeC2CPNRSvc.exe 1912 Services 0 1,160 K
dsiwmis.exe 2004 Services 0 3,200 K
ePowerSvc.exe 2036 Services 0 3,568 K
svchost.exe 1944 Services 0 10,464 K
GREGsvc.exe 2076 Services 0 1,404 K
mbamscheduler.exe 2128 Services 0 5,924 K
mbamservice.exe 2264 Services 0 77,672 K
capiws.exe 2304 Services 0 14,004 K
avgnsa.exe 2432 Services 0 12,912 K
avgemca.exe 2440 Services 0 2,544 K
UpdaterService.exe 2576 Services 0 1,992 K
ToolbarUpdater.exe 2612 Services 0 8,564 K
WLIDSVC.EXE 2652 Services 0 11,764 K
WLIDSVCM.EXE 2784 Services 0 900 K
loggingserver.exe 2852 Services 0 1,940 K
conhost.exe 2860 Services 0 932 K
atieclxx.exe 3064 Console 1 4,112 K
wmpnetwk.exe 3852 Services 0 13,264 K
SearchIndexer.exe 3520 Services 0 39,524 K
WmiPrvSE.exe 4048 Services 0 5,072 K
mbam.exe 3964 Console 1 44,492 K
dwm.exe 3288 Console 1 28,192 K
taskhost.exe 3144 Console 1 11,088 K
explorer.exe 3564 Console 1 48,140 K
RAVCpl64.exe 2752 Console 1 5,188 K
SynTPEnh.exe 1124 Console 1 7,148 K
ePowerTray.exe 3548 Console 1 4,940 K
ipoint.exe 1308 Console 1 7,320 K
StikyNot.exe 3756 Console 1 7,796 K
Skype.exe 3940 Console 1 79,880 K
LManager.exe 3300 Console 1 7,608 K
vprot.exe 3448 Console 1 17,444 K
iTunesHelper.exe 1152 Console 1 4,876 K
avgui.exe 2676 Console 1 14,564 K
MMDx64Fx.exe 1236 Console 1 1,600 K
iPodService.exe 4368 Services 0 3,332 K
LMworker.exe 4416 Console 1 1,668 K
unsecapp.exe 4908 Console 1 3,404 K
SynTPHelper.exe 4632 Console 1 1,388 K
ePowerEvent.exe 4556 Console 1 1,688 K
ctfmon.exe 4520 Console 1 1,764 K
MOM.exe 5028 Console 1 5,672 K
CCC.exe 4988 Console 1 5,164 K
mmc.exe 2540 Console 1 8,424 K
svchost.exe 4996 Services 0 3,644 K
svchost.exe 5308 Services 0 10,396 K
dllhost.exe 5304 Services 0 2,968 K
wlmail.exe 6732 Console 1 165,256 K
wlcomm.exe 6692 Console 1 18,668 K
avgcsrva.exe 1636 Services 0 47,964 K
wuauclt.exe 5716 Console 1 4,340 K
chrome.exe 6816 Console 1 110,416 K
chrome.exe 6948 Console 1 150,668 K
chrome.exe 4320 Console 1 20,212 K
cmd.exe 6496 Console 1 2,000 K
conhost.exe 5136 Console 1 3,796 K
mspaint.exe 4444 Console 1 23,320 K
svchost.exe 3932 Services 0 4,376 K
calc.exe 6516 Console 1 7,592 K
WINWORD.EXE 5180 Console 1 76,904 K
OSPPSVC.EXE 6088 Services 0 10,900 K
splwow64.exe 7164 Console 1 4,608 K
chrome.exe 8004 Console 1 120,552 K
chrome.exe 5872 Console 1 69,384 K
chrome.exe 528 Console 1 46,624 K
mmc.exe 7040 Console 1 7,192 K
tasklist.exe 7192 Console 1 5,476 K
clip.exe 6060 Console 1 2,596 K
WmiPrvSE.exe 7196 Services 0 6,092 K