Read that document. Ripple signals are an 'added bonus', not a core service like actually providing power:
Disclaimer: Orion uses reasonable endeavours to maintain its ripple injection and electricity delivery systems, but
these services are not guaranteed. From time to time, intended ripple signals may not be provided or may occur at
times that differ from published switching times. Orion expressly disclaims any liability for direct or indirect losses
associated with the use or otherwise of its ripple signals.
Again, on top of that, by connecting load to a CN16 or CN19 channel, you are agreeing for it to be powered 16/19 or more hours per day. Being energised 24/7 is not a failure; it is a normal operating condition for the full length of September-April; more than half the year.
You might have an argument (if not for the disclaimer) with a night-only type rate on a night store heater. However, these are rapidly going out of fashion, and lines companies also want to be out of the business of providing time switch services. They are also thermostat-controlled limiting the effect of additional operating hours, albeit less effectively than hot water cylinders.