Dial111: Try removing the cmos battery to reset the mobo. Also, I know you've tried but this sounds like a faulty PSU, have you got yet another you could try.
Next time it doesn't boot unplug all PSU cables except for 24 pin and mains then try jump starting the PSU with a paper clip.
So you mean unplug from vidcard and ssd so only motherboard is connected?
Already tried a spare psu and didn't work either so having a hard time thinking it must be psu. New component draw less power.
It could be MB 24pin bracket contacts are bad though but do not have stuff to check. Already contacted a pc repair shop to look at it coming monday