mentalinc:
Not sure why you'd turn off one of the bottles?
They're designed to be both available so if you have all the hobs on, and someone having a shower/using hot water there is enough gas pressure available to meet the needs.
They should connect with a device that shows when the bottle is empty to reorder.
typically they are on a change over valve, which swaps to the other bottle when empty and displays an empty indicator. its doesn't run both at the same time.
some people don't have the auto change over valve, so when first bottle run out they run out. that way they know to order another. otherwise they tend to forget to check and end up with both empty. also for those with big burners or multiple heaters they can run both bottles at the same time as a single bottle can struggle to supply enough gas.