CokemonZ:
So after shuffling a couple of drives around I have found the issue with storage spaces behaving weirdly.
One of the new sata cables I put in was dodgy, which was causing drive write failure attempts on one drive.
Who would have thought.
Anyway - thanks for everyones help - today - storage spaces, tomorrow (or when I get a couple of days off and want a project) Unraid.
So what is your final configuration and performance? Did you leave it configured as 'battery backed'?