I did soemthing similar for the top architraves in 2 rooms. I left the og stuff untouched, cut thru the old board like gib, then when the new gib was installed i added a run of thin timber that matches to create a 'more epic' alchitrave. You cant tell the difference but depends on what you have installed as it wouldnt work with every look. Around windows I would think works too but less likely to match it. My window trim actually all came off easily, and I could then insulate them really well with the foam at that point.